It certainly is tempting. You have tile on the wall with broken grout and need to patch it up. Removing and replacing the grout will take all weekend. A tube of caulk costs $5, and you could probably cover those gaps in 15 minutes. So can you caulk over grout? It sure would be easier.
While caulking over grout is a fairly common quick fix, there are several reasons not to recommend it. It seems to work sometimes, but when it doesn’t work, you end up with two problems.










